GT Courtesy Listing

Title:

Chemical Functionalization as an Approach to the Modification of the Electronic and Magnetic Properties of Graphene

Speaker:

Prof. Robert C. Haddon

Affiliation:

University of California at Riverside

When:

Tuesday, May 17, 2011 at 3:00:00 PM   

Where:

Marcus Nanotechnology Building

Host:

Gina Adams
gina.adams@mrsec.gatech.edu

Abstract

We report the application of a range of chemical reactions to the basal plane functionalization of graphene, including the Diels-Alder reaction – in which we show that graphene can act as both diene and dienophile – and the addition of nitrophenyl radicals. The chemical formation of covalent carbon-carbon bonds involving the basal plane carbon atoms offers an alternative approach to the control of the electronic properties of graphene; the transformation of the carbon centers from sp2 to sp3 introduces a barrier to electron flow by saturating the carbon atoms and opening a band gap which potentially allows the generation of insulating and semiconducting regions in graphene wafers. In this talk I will discuss our work on the electronic and magnetic properties of chemically modified graphene.


Biography

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