SUMMARY

Thermal energy storage (TES) is a promising technology for the Energy Transition. Low grade heat is valuable for many everyday applications: indoor heating and cooling, hot water, refrigeration, etc. Heat pumps (HPs) move heat up a thermal gradient (from cold to hot) with an input of energy. Integrating TES into a HP grants flexibility to dispatch the stored heat as needed. When operating a HP against a fluctuating temperature body (i.e., outdoor ambient air temperature), TES provides an isothermal heat source that enables more efficient HP operation to its reduce energy consumption without sacrificing thermal comfort. This work explores the thermodynamic limits of HP-TES and it was found that TES temperatures equal to the application temperature leads to the highest potential for energy savings and peak demand reduction. This HP-TES system was then modeled in a building thermal energy simulation where the same findings emerge: a TES temperature near the application temperature shows the highest potential. A common method of achieving an isothermal TES is to incorporate phase change materials (PCMs) that store heat through the enthalpy of phase change. Salt hydrates are valued for their high volumetric storage density and low cost. This work explores the Brunauer-Emmett-Teller method to model sodium sulfate, but this salt was found to be incompatible with this reduced order method. Salt hydrates also exhibit low thermal conductivity which limits their direct use in TES. This work develops salt hydrate-graphite composite PCMs with improved thermal conductivity, however a tradeoff between energy storage capacity and thermal power density was seen. The composite PCMs were experimentally tested in a TES device and the improved thermal properties demonstrate their potential for use in simple TES architectures. Overall, this work evaluated TES systems from a holistic perspective, spanning several orders of magnitude, both energetically and spatially.